High activity of CeO2-TiO2 composites for deep oxidation of 1,2-dichloroethane

作者：Jialu Wang,Zhinan Shi,Renxian Zhou

摘要：CeO2-TiO2 catalysts prepared by different methods were investigated for deep oxidation of 1,2-dichloroethane(DCE),as a typical representative of the chlorinated volatile organic compounds(CVOCs).Characterization analysis reveals that CeO2-TiO2 catalysts prepared by sol-gel and coprecipitation methods exhibit higher specific area,CeO2 and TiO2 particles are highly dispersed into each other and the reducibility and mobility of active oxygen species are obviously promoted due to the strong interaction between the two catalysts CeO2 and TiO2,resulting in higher catalytic activity for DCE oxidation to and less chlorinated byproduct.The high calcination temperature would lead to the formation of a new monoclinic phase Ce0.3Ti0.7O2 and sintering,which is the main reason for the catalytic activity for DCE oxidation markedly decreases.

发文机构：Institute of Catalysis

关键词：CeO2-TiO2catalystsSynergismChlorinatedVOCsCatalyticoxidationRareearths

分类号： X701[环境科学与工程—环境工程]TB33[一般工业技术—材料科学与工程]